Smithsonian Institute Archive has a strong warning against trying to remove a photograph that is stuck to glass yourself. That includes trying to separate a photograph from glass by putting it into a microwave oven or a freezer, or heating it up with a hairdryer. Instead, they recommends that restoration of such photographs should be left to experienced photo restoration professionals.
In cases when a photograph cannot be removed form glass or if it is too damaged by shattered pieces, moisture and debris, a photograph can be restored by making a high quality scan and digital retouching.
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